3072. SCHENCK, R., AND MEYER, K. [Carbide Studies in the Methane Synthesis. IV. The Chemistry of Double Carbide.] Ztschr. anorg. Chem., vol. 243, 1940, pp. 259-268; Chem. Abs., vol. 34, 1940, p. 4974. From the carbonization isotherms at 800° for 7 mixtures of Fe and W, a space model for the overall isotherms was prepared. By projection on the base, 6 fields were obtained, having the following compositions: A, consisting of the double carbide Fe6W6C6 and γ-Fe; B, a-Fe, W, and Fe6W6C6; C, η-W, Fe6W6C6, and FeW23C7; D, mixed crystals of W (containing C and Fe) and FeW23C7; E, a-FE (containing W); F, a- and β-Fe (stable). Fe6W6C6 is considered a compound of Fe3C and W2C; it decomposes above 800° into graphite and mixed crystals. Other carbides are indicated by vapor-pressure measurements on the CH4 phase. SCHENCK, R., KURZEN, F., AND WESSELKOCK, H. [Activation of Metals by Foreign Substances. II.] See abs. 3067. SCHENCK, R., LAYMANN, A., AND JENCKEL, E. [Equilibrium Investigations in the Reduction, Oxidation, and Carburization Processes of Iron. XIII.] See abs. 3062. SCHENCK, R., MEYER, K., AND MAYER, K. [Carbide Studies in the Methane Synthesis. III.] See abs. 3071. |