3062. SCHENCK, R., LAYMANN, A., AND JENCKEL, E. [Equilibrium Investigations in the Reduction, Oxidation, and Carburization Process of Iron. XIII.] Ztschr. anorg. Chem., vol. 235, 1937, pp. 65-76; Chem. Abs., vol. 32, 1938, p. 2418. System Fe-O-Ca was studied by determining the decomposition diagrams of Fe2O3-CaO mixtures at 900° and with a range of 23-79% CO2 in the atmosphere. The following phases are found to exist: Fe3O4, wüstite, CaO.Fe3O4, and (CaO)2.Fe2O3. In the presence of even small concentrations of CO in the atmosphere, the phase CaO.Fe2O3 cannot exist. The results are plotted with triangular coordinates. |