3043. SCHEFFER, F. E. C., DOKKUM, T., AND AL, J. [Dissociation of Methane.] Rec. trav. chim., vol. 45, 1926, pp. 803-816; Chem. Abs., vol. 21, 1927, p. 690. Continuous current method has been replaced by one of circulation of the gas. Both C2H4 and CH4 were used as a source of activated C obtained in the presence of Ni as a catalyst. An account of the preparation of the gas and manner of carrying on experiments is outlined carefully. The reaction was studied 480°-680°, since below these temperatures, C reacts with the Ni catalyst. The substance formed is stable at 340°-420° and has an exothermic formation. Mathematical deductions of the 2 equilibrium curves are given from data obtained at atmospheric pressure and different temperatures. |