3030. ---------------. [SASTRI, M. V. C., AND SRIKANT, H.] Adsorption of Nitrogen at Elevated Pressures on a Promoted Iron Synthetic-Ammonia Catalyst. Current Sci., vol. 19, 1950, p. 343; Chem. Abs., vol. 45, 1951, p. 7406. Adsorption isotherms were determined for N2 on an Fe-K2O-Al2O3-TiO2 catalyst at 7 temperatures 50°-350°, and 15-50 atm. Adsorption at lower pressures (20 and 30 atm.) exhibits only 2 maxima at 150° and 300°, respectively; however, at 50 atm., 3 maxima are observed, 100°, 200°, and 300°. For an adsorption of 0.05-0.15 cc. per gm. at 20 atm., a value of 23 kcal. is obtained for the isobaric heat of adsorption. |