3029a. SASTRI, M. V. C., AND SRIKANT, H. Adsorption of Hydrogen at Elevated Pressures on a Promoted Iron-Synthetic Ammonia Catalyst. Current Sci., vol. 19, 1950, p. 313; Chem. Abs., vol. 45, 1951, p. 9,993. Static volumetric method for measuring adsorption of gases by solids at elevated pressures was developed, and the adsorption of H2 on a Fe-K2O-Al2O3-TiO2 catalyst at temp. 50°-350° and pressure 15-50 atm. was studied. 2 distinct types of activated adsorption of H2 were found, 1 with a maximum at about 150°, the other with a maximum at about 300°. The results indicate the superposition of adsorption on the chemisorption of the H2. |