2942. ---------------. [RUHRCHEMIE, A.-G.] [Course of the Pressure Synthesis When Using an Initial Gas Rich in Carbon Monoxide.] FIAT Reel K-20, no date, frames 11-17; PB 70,211; TOM Reel 287. Gas used consisted of CO:H2=1:1. Higher yields of liquid products were obtained than with normal synthesis gas. In order to obtain a good conversion of the CO, temperatures up to 215° were used. The total product consisted of about equal parts of gasoline, middle oil, and paraffin, the latter being about 8% less than in normal synthesis. The olefin content of the gasoline was 32-36 vol. % and that of the middle oil 24-27%. With a catalyst containing Co, 100:ThO2, 15; kieselguhr, 600; and a gas rich in CO, considerably better results were obtained. The conversion of CO was 92% and the ratio of liquefaction 89%. The content of paraffin was 17% higher than with the normal catalyst. |