2929. RUFF, O., AND BORMANN, W. [Investigations at Higher Temperatures. V. Manganese and Carbon.] Ztschr. anorg. Chem., vol. 88, 1914, pp. 365-385; Chem. Abs., vol. 9, 1915, p. 435. The solubility of C in Mn is 6.82% at 1,312°, 6.93% at 1,427°, 7.05% at 1,492°, and 7.12% at 1,525°; the latter boils at 30 mm., and the vapor in equilibrium contains 1.94% C. Pure Mn boils at 1,510° at 30 mm. Since the vapor pressure of C up to 3,000° is small, the vapor in equilibrium with Mn melts probably contains its C as carbide; it is also probable that all of the C contained in the melt is combined as carbide. |