2925. ---------------. [RUFF, O., AND GERSTEN, E.] [Carbides of Manganese and Nickel.] Ber. deut. chem. Gesell., vol. 46, 1913, pp. 400-413; Chem. Abs., vol. 7, 1913, p. 1848. Molecular heats of formation of Mn3C=-12.9±2.14, Fe3C=-15.3±0.2 and Ni3C=-394±10 cal. The Ni3C is very unstable and is not obtained in a pure condition. Mn3C is comparatively stable and is obtained by heating Mn in a C crucible with C at 1,600° in an electric vacuum furnace. Ni3C is formed at 2,100°. The maximum amount of C found in the carbide is 6.42%. |