2912. RÖTTIG, E. [New Substances With Spinel Structure.] Angew. Chem., vol. 62, 1950, p.87. CuFe5O8, analogous to LiAl5O8 and LiFe5O8, was made at 1,200° C. Its θ=390° and a=8.389±0.003 Å. This is a spinel. CuFe2O4, made at 600°, has θ=490° and is psuedo-tetragonal with a=8.44 Å, c/a=0.975. Cu+Fe Mixtures of CuFe2O4 and 2 Fe2O4 have θ=440° and a spinel structure with a=8.377±0.003 Å. CuAl5O8 is not quite cubic. CuAl2O4 and CuCr2O4 are not cubic, contrary to the literature. Li+, Cu+, or Ti4+ spinels could not be obtained. LiFeTiO4 and LiCrTiO4 are spinels. LiAlTiO4 is not cubic. LiFeTiO4 is ferromagnetic with θ=130°. ROUDEBUSH, B. See abs. 626. |