2818. RIDEAL, E. K. Note on a Simple Molecule Mechanism for Heterogeneous Catalytic Reaction. Proc. Cambridge Phil. Soc., vol. 35, 1939, pp. 130-132. Proposed mechanism involves 2 assumptions: (1) That surface catalytic reactions take place between a chemisorbed radical or atom and a molecule derived from the gas phase; (2) that in the interaction between the 2 species the covalent bond between the chemisorbed constituent and substrate either is not broken or is converted into the van der Waals bond. |