2763. RACINE, J. [Study of the Reducing Properties of Methane.] Compt. rend., vol. 220, 1945, pp. 823-825; Chem. Abs., vol. 40, 1946, p. 3672. Reduction of some metallic oxides by CH4 was studied at temperatures up to 1,100°. The following were reduced: CuO, ZnO, CdO, HgO, PbO2, Cr2O3, MoO3, NiO, WO3. The following were not reduced: MgO, CaO, Al2O3. MnO is converted to a carbide at 800°. C2H2 appears at 825°. Fe2O3 is reduced to an unidentified oxide at 400°, and to Fe at 800°; a carbide is formed at 1,050°. C2H2 is formed at 800°; C is deposited at 1,000°. Co2O3 is reduced to CoO at 450°, and to Co at 800°; a carbide is formed at 1,000°. |