2752. PRING, J. N., AND HUTTON, R. S. Direct Union of Carbon and Hydrogen at High Temperatures. Jour. Chem. Soc., vol. 89, 1906, pp. 1591-1601; Proc. Chem. Soc., vol. 22, 1906, p. 260; Chem. Abs., vol. 1, 1907, pp. 178, 550. Purest C rods on being heated in H2 gave about 0.25% CH4 at 1,200°-1,350°, 0.4% at 1,700°, and about 1% at 2,700°. (See Bone and Jerdan, Jour. Chem. Soc., vol. 71, 1897, p. 41; vol. 79, 1901, p. 1042.) Traces of C2H2 were formed at 1,700°, measurable quantities at 1,800°, 0.88% at 2,000°, 3.35-4.2% at 2,500°, and 2.75-3.03% at 2,700°. |