2706. ---------------. [PINGAULT, P.] [Cementite.] Ann. chim., vol. 20, 1933, pp. 371-438; Chem. Abs., vol. 28, 1934, p. 3040. Cementite (Fe3C, 6.65-6.70%) containing 0.05% of free C was prepared by heating Fe with NaCN at 600°-650°; it also may be prepared by electrolysis of fused NaCN with Fe electrodes or by passing coal gas or CH4 over Fe at 850°-975°. Fe3C reduced by H2 has a density at 0° of 7.30, is not attacked by H2 under atmospheric pressure at 450°, is thermodynamically unstable at ordinary temperatures, and begins to decompose near the melting point of cast Fe. The equilibria in the system Fe-Fe3C-O2 have been studied at 830°-1,000°. ----------. See abs. 472. PINKEL, I. I. See abs. 3295. |