2671. ---------------. [PICHLER, H.] [Working Up Fischer-Tropsch Products.] Brennstoff-Chem., vol. 16, 1935, pp. 404-406; Ges. Abhandl. Kenntnis Kohle, vol. 12, 1937, pp. 481-486; Chem. Abs., vol. 30, 1936, p. 3980. Synthetic-paraffin oil boiling at over 250° has been converted at 500°-600° and atmospheric pressure without carrier gas, in one step, into gaseous olefins and volatile unsaturated and aromatic hydrocarbons with 75% yields. The remainder consisted of saturated gaseous hydrocarbons, unconverted paraffins, and aromatic tar. Below 500°, conversion was small. Above 600°, yields of gaseous olefins predominated. Example: 20% olefins at 550° and 0.4 sec. reaction time in small tubes, 60% at 700° and 0.14 sec. |