2625. ---------------. [PETERS, K., AND WINZER, K.] [Preparation of Light Naphtha From Kogasin II by Cracking.] Brennstoff-Chem., vol. 17, 1936, pp. 301-306; Ges. Abhandl. Kenntnis Kohle, vol. 12, 1937, pp. 506-516; Coal Carbonisation, vol. 2, 1936, p. 205; Chem. Abs., vol. 31, 1937, p. 1992. Cracking at 465°-570° and pressures to 100 atm. has been studied at throughputs up to 150 cc. oil/min. Cracking was assisted by H3PO4 catalyst. The proportion of gaseous to liquid products varied between 1:2 and 1:6 up to 530° and at 560° attained 1:1, as compared with cracking at atmospheric pressure in a Pythagoras tube up to 740° where proportions ranged 2:1-6:1. Pressure cracking yielded unsaturated compounds in smaller amount, the naphtha obtained, however, being highly unsaturated. Treatment with C2H4 in the presence of H3PO4 catalyst did not improve the octane number, although C2H4 did. |