2599. PEASE, R. N. Catalytic Combination of Ethylene and Hydrogen in the Presence of Metallic Copper. I. Measurements of Reaction Velocity and Adsorption Isotherms at 0° and 20°. Jour. Am. Chem. Soc., vol. 45, 1923, pp. 1196-1210; Chem. Abs., vol. 17, 1923, p. 2220. Kinetics of the catalytic combination of H2 and C2H4 have been studied at 0° and 20° in the presence of Cu. The reaction velocity and adsorption isotherms have been determined. Within limits, the velocity increases with the H2 concentration but decreases as the C2H4 concentration increases. The temperature coefficient of the reaction velocity/10° rise between 0° and 20° is 1.62, indicating that diffusion does not play a dominant part. |