2578. PARTINGTON, J. R., AND SHILLING, W. G. Water-Gas Equilibrium. Jour. Soc. Chem. Ind. (London), vol. 44, 1925, pp. 149-150T, 242T; Chaleur et ind., vol. 7, 1926, p. 683; Chem. Abs., vol. 19, 1925, pp. 1769, 2267. To determine the value of K in the equation ([CO2]X[H2])/([CO]X[H2O])=K, the value –0.4647 has been selected for the integration constant in the equation log K=-(2226/T)+1.077 log T-0.03898T+0.06133T2+C. Values for K for each 100° interval from 1,100° abs. to 1,800° abs. are given. The equation and curve presented represent the most reliable data at present available. Previous equations were based on inaccurate specific-heat data. |