2545. OTA, N. Water Gas by the Reaction of Methane and Carbon Dioxide. I. Catalysts. Jour. Soc. Chem. Ind. (Japan), vol. 45, 1942, pp. 284-290; Chem. Abs., vol. 43, 1949, p. 1944. Equivalent mixture of CH4 and CO2 under atmospheric pressure was passed through a layer of catalyst at 700°-800° to obtain CO and H2. Catalysts composed of Ni and various oxides and carriers in different ratio were used, and, among those tried, 1 containing Ni, MgO, and kieselguhr in the ratio 1:1:4 gave the best yield of CO+H2 at 700° with the least formation of C on the catalyst. |