2472. ---------------. [NIKITIN, V. M.] [Byproducts of Methanol Synthesis.] Org. Chem. Ind. (U.S.S.R.), vol. 2, 1936, pp. 382-387; Chem. Abs., vol. 31, 1937, p. 1759. Study of the properties of all combinations of binary systems of iso-BuOH, iso-BuOAc and H2O includes mutual solubilities at various temperatures, equilibrium of liquid and vapor phases, azeotropic mixtures, density and n. The experimental results are tabulated, graphed and discussed. With increasing temperature the solubility of iso-BuOH in H2O decreases and that of H2O in iso-BuOH increases. The azeotropic mixture is composed of 68 mol. % of H2O and 32 mol. % of iso-BuOH. |