2389. ---------------. [NATA, G.] [Preparation of Mono- and Polyhydroxy Alcohols.] Chimica e industria, vol. 24, 1942, pp. 389-393; Chem. Zentralb., 1943, I, p. 2242; Chem. Abs., vol. 38, 1944, p. 4252. Some new methods of large-scale technical synthesis of mono- and poly-OH alcohols from water gas (MeOH synthesis) and from CO2 and H2 are described. In the latter case, the CO2 is a byproduct in the production of Ca (NO3)2 from CaCO3; the H2 is produced by electrolysis. The yield of MeOH synthesized by this process reaches 92% as compared with 86-89% by the usual water-gas process. |