2255. ---------------. [MEYER, W. F.] [Cobalt-Carbon System.] Metallwirtschaft vol. 17, 1938, pp. 413-416; Chem. Abs., vol. 32, 1938, p. 4866. When illuminating gas is heated with Co in the temperature range 230°-470° the CO dissociates under the catalyzing effect of Co and a mixed crystal forms. The crystal is attainable only between 230° and 270°, when a diffusion equilibrium exists; above this range the outward diffusion of C is too rapid. Between 500° and 1,200°, Co also catalyzes CO dissociation and a mixed crystal forms. Between 500° and 800°, benzene as well as illuminating gas acts on Co to form a stable Co carbide, whose lattice structure corresponds to that of Fe3C; the lattice dimensions, to an accuracy of ±0.5% are a=4.52 Å., b=5.08 Å., c=6.73 Å. 11 refs. ----------. See abs. 1935. |