2254. MEYER, W. F. [Investigations of Cobalt and the System Cobalt-Carbon.] Ztschr. Krist., vol. 97, 1937, pp. 145-169; Chem. Abs., vol. 31, 1937, p. 8339. X-ray photographs at temperatures up to 1,100° show no 2d transformation of Co. On heating with illuminating gas up to 230°-270° a mixed crystal of variable composition is formed, which is unstable at room temperature. At 500°-800° stable Co3C is formed, analogous to Fe3C. Its unit cell dimensions are a=4.52, b=5.08, c=6.73 Å. Heating with benine and CO also produces Co3C. |