2249. MEYER, K., AND HORN, O. [Reaction of Carbon Monoxide and Hydrogen in Coke-Oven Gas With Molybdenum Catalysts.] Ges. Abhandl. Kenntnis Kohle, vol. 11, 1934, pp. 389-394; Chem. Zentralb., 1934, II, p. 875; Chem. Abs., vol. 29, 1935, p. 6732. No reduction of CO occurs at 1 atm. At 100 atm. reduction to CH4 occurs, but a higher temperature (400°) is needed with a Mo than with a Ni catalyst. Mo is activated by Mn, Cr, Th, and Cu but not by W. Alkali destroys the activity. Mo and Mo-Th catalysts for the hydrogenation of C2H4 are not poisoned by H2S. |