2244. ---------------. [MEYER, G., AND SCHEFFER, F. E. C.] [Dissociation of Carbon Monoxide.] Rec. trav. chim., vol. 46, 1927, p. 754-762; Chem. Abs., vol. 22, 1928, p. 714. Equilibria were measured at 500°-750° by passing CO over a Ni catalyst. Equilibrium constants for C+CO2 D 2CO are expressed by log Kc=(8,829/T)-7.067 and log Kp=(9,217/T)-9.369. True equilibria were not obtained with a Ni catalyst until it was heated well above 420° to break up Ni carbide. |