2217. MAYER, M., AND ALTMAYER, V. [Equilibrium of Methane.] Ber. deut. chem. Gesell., vol. 40, 1907, pp. 2134-2144; Jour. Chem. Soc., vol. 92, 1907, I, p. 457. From equilibrium data calculated on the basis of investigations of the reaction C+2 H2=CH4 in the presence of Ni or Co at temperature 470°-620°, doubts are expressed that Bone and Jerdan (abs. 296) could have effected the synthesis of CH4 at 1,200°. Probably the C employed contained impurities that yielded CH4. |