2205. KODAMA, S., MATSUMURA, S., YOSHIMORI, K., NISHIBAYASHI, Y., KADOTA, N., AND IWAMURA, E. Physicochemical Studies on Gasoline Synthesis. XIII. XV. Influence of Potassium Carbonate and Boric Acid on the Activated Adsorption of Hydrogen and Carbon Monoxide on Iron Catalysts. Jour. Soc. Chem. Ind. (Japan), Sec. vol. 51, 1948, pp. 80-100; Chem. Abs., vol. 44, 1950, p. 9136. By adding K2CO3 to the catalyst containing 100 Fe + 25 Cu + 2 Mn + 125 kieselguhr, activated adsorption of CO above 200° is increased, while that of H2 is not, especially when 6% K2CO3 is added. By adding H3BO3 to the same catalyst, adsorption of CO is decreased and adsorption of H2 increased at 200°. When 20% H3BO3 and 2% K2CO3 are added, adsorption of both CO and H2 at 200° is increased. The above tendency conforms with results of gasoline synthesis with the same catalyst: Increase in the length of synthesized molecules and of the I values of the oil by adding K2CO3 or a decrease with H3BO3, and an increase in yield by the addition of both. |