2203. ---------------. [KODAMA, S., MATSUMURA, S., TARAMA, K., ANDO, T., AND YOSHIMORI, K.] Physicochemical Research on Gasoline Synthesis. X. Adsorption of Carbon Monoxide on Cobalt, Cobalt-Kieselguhr, and Cobalt-Kieselguhr-Thoria Catalysts. Jour. Soc. Chem. Ind. (Japan), vol. 45, 1944, pp. 1-5; Chem. Abs., vol. 43, 1949, p. 2413. Adsorption of CO was measured at 0°-250°. In all cases, adsorption accompanied by decomposition of CO and formation of metallic carbide took place above 110° and ordinary activated adsorption took place below 110°. The addition of kieselguhr and ThO2 greatly increased the number of centers of activity and promoted the formation of carbide. |