2202. ---------------. [KODAMA, S., MATSUMURA, S., TARAMA, K., ANDO, T., AND YOSHIMORI, K.] Physicochemical Research on Gasoline Synthesis. IX. Velocity of Adsorption of Hydrogen by a Composite Iron Catalyst. Jour. Soc. Chem. Ind. (Japan), vol. 45, 1942, pp. 254-258; Chem. Abs., vol. 43, 1949, p. 2413. Similar experiment was carried out with a catalyst containing Fe, Cu, Mn, and infusorial earth in the ratio 100:25:2:125, respectively, which was reported by Tsuneoka and others (abs. 1885) to be a good catalyst in gasoline synthesis. Results similar to the case of pure Fe were obtained, except that the t/x-t curve was irregular at 25° and 60°, and above 100° it was a broken line, showing that the adsorption of H2 above 100° conformed to the second order reaction velocity equation. In comparison with the Fe-infusorial earth catalyst, there was no marked change in the amount of H2 adsorbed and its change with temperature at higher temperature, but below 100° the amount of H2 adsorbed increased. This increase is considered to be caused by Cu. |