2159. MAIER, C. G. Reduction of Cuprous Oxide by Carbon Monoxide. Bureau of Mines Rept. of Investigations 2926, 1929, 7 pp.; Chem. Abs., vol. 23, 1929, p. 3621. Presence of less than 0.1 mm. CO pressure in an atmosphere of otherwise pure CO2 will act reducingly toward Cu2O below 1,064°. The equilibrium changes with temperature in such a way that below 900° decreasing quantities of CO suffice to reduce Cu2O. At temperatures near and above the melting point of Cu, a partial pressure of 7.6 mm. CO in otherwise pure CO2 should reduce the dissolved CuO to 0.008%. |