2142. LOSANITSCH, S. M., AND JOVITSCHITSCH, M. Z. [Chemical Synthesis by Aid of the Dark Electric Discharge.] Ber. deut. chem. Gesell., vol. 30, 1987, pp. 135-139; Chem. Zentralb., 1897, I, p. 354; Jour. Chem. Soc., 1897, I, p. 179. Using a current of 3-5 amp. and 70 v., a mixture of CO and H2O yields HCOOH, while CO2 and H2O give HCOOH, and O2; CO and H2 yield CH2O, which polymerizes; CO2 and H2 yield HCOOH. On subjecting mixtures of equal volumes of CH4 and CO to the silent discharge, acetaldehyde and its condensation and polymerization products are obtained. |