2135. ---------------. [LONGUET-ESCARD, J.] [Structure of Several Hydroaluminates of Nickel.] Jour. chim. phys., vol. 47, 1950, pp. 238-243; Chem. Abs., vol. 44, 1950, p. 7612. Addition of NaOH to a mixture of nitrates or chlorides of Ni and Al rich in Ni salts resulted, after washing and drying, in the formation of a hydroaluminate of Ni. An X-ray study was made of these types of compounds. The X-ray results were consistent with a structure composed of layers of hydroxyl ions and layers of metallic ions. The role of the Al might be to stabilize this type of structure by substitution for a small number of Ni ions. Such hydroaluminates of Ni have been used in the preparation of catalysts for the Fischer-Tropsch synthesis. ----------. See abs. 1062. |