2113. LIANDER, H. Utilization of Natural Gases for the Ammonia Process. Trans. Faraday Soc., vol. 25, 1929, pp. 462-472; Chem. Abs., vol. 23, 1929, p. 4779. Possible reactions of CH4 with O2, H2O, and CO2 were calculated from the Nernst heat theorem. Experiments were made by heating CH4 and O2, with and without Ni catalysts, to 550°-850°. With no catalyst the products are CO2 and H2O; with catalyst H2, CO, and CO2. Conclusion: Natural gas, air, and steam passed over a suitable catalyst at 1,000° would yield gas that could be used as a source of H2 and N2 for NH3 synthesis. LIANG, S. C. See abs. 3337, 3338. LIBERMAN, A. L. See abs. 1706. LILLE, R. See abs. 1058. |