2035. LACY, B. S., DUNNING, R. G., AND STORCH, H. H. Equilibrium in the Synthesis and Decomposition of Methanol. Jour. Am. Chem. Soc., vol. 52, 1930, pp. 926-938; Chem. Abs., vol. 24, 1930, p. 2943. Average equilibrium constants for the reaction 2 H2+CO=CH3OH, measured at 300° and 250° from both sides, and at 200° from the synthesis side, all at 50 atm. pressure, were 1.9 x 10-4, 1.25 x 10-3 and 3 x 10-2, respectively, and 1.8 x 10-3 at 250° and 20 atm. from the synthesis side. Similar constants were found by calculations, using the reactions of HCOOMe and H2 and of MeOH and CO. (See abs. 560, 2448, and 3209.) |