2017. KUROKAWA, M., AND TAKENAKA, Y. [Thermal Effect on the Catalyst of the Water-Gas Reaction.] Jour. Soc. Chem. Ind. (Japan), vol. 40, 1937, B, p. 347; Chem. Abs., vol. 32, 1938, 1554. Fe2O3 catalyst generally used for the conversion of CO and H2O to H2 and CO2 is impaired by the heat of the exothermic reaction. The conversion at 450° was measured with promoted Fe2O3 catalysts before and after heating to 850°. The resistance of the catalyst to heat was greatly improved by additions of Cr2O3 and MgO. The optimum ratio Fe2O3 : Cr2O3 : MgO was 1:01:0.03. The catalyst obtained by precipitation with KOH was better than that with NH3. |