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1911. KODAMA, S., TAHARA, H., NAKBAYASHI, T., AND HONGO, M. Gasoline Synthesis From Carbon Monoxide and Hydrogen at Elevated Pressures. IX. Influence of the Composition of the Raw Gas on the Reaction. Jour. Chem. Soc. Japan, Ind. Chem., sec., vol. 51, 1948, pp. 23-24; Chem. Abs., vol. 44, 1950, p. 9135.
With H2:CO ratios in the raw gas of 1.1, 2.0 or 2.7 oil yields are 61, 57, or 50 gm. per m.3, respectively, with H2:CO consumption ratios of 0.7, 1.0, or 1.4 respectively with a catalyst of Fe+Cu25+kieselguhr 125+K2CO3% at 10 kg. per cm.2 pressure and 210°. Under similar conditions the addition of 16% CO2 (CO:H2=1:1) decreases the oil yield, but 5% CO2 does not. A determination of N (CO:H2=1:2) up to 33.4% does not affect the yield for practical purposes.