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1563. ---------------. [INSTITUTE OF GAS TECHNOLOGY.] Fischer-Tropsch Process, an Annotated Bibliography. Rept. for Tech. Sec., Postwar Planning Cooperating Com., October 1945, p. 23.
Compilation of every published type of
Fischer-Tropsch cobalt catalyst
Composition
|
Ratio of constituents, wt. basis |
Reaction temp., °F. |
Yield of primary product liquid, and solid hydrocarbons, gal./1,000 ft.3 |
Remarks |
Co................................ |
100 |
410 |
0.33 |
|
Co-Al........................... |
100:20 |
419 |
.07 |
|
Co-Cr.......................... |
100:20 |
419 |
.10 |
|
Co-Mg......................... |
100:20 |
419 |
.34 |
|
Co-Mn......................... |
100:20 |
419 |
.47 |
|
Co-ThO2...................... |
100:18 |
392 |
.10 |
|
Co-Zn.......................... |
100:20 |
419 |
.31 |
|
Co-Cu-ThO2................ |
100:33:15 |
482 |
.09 |
|
Co-Cu-ThO2................ |
100:12:2 |
387 |
16.20 |
|
Co2O3-MnO2-CuO...... |
100:75:50 |
523 |
.03 |
|
Co-Mn-kguhr............... |
100:15:- |
392 |
.90 |
|
Co-ThO2-kguhr............ |
100:18:100 |
374 |
.97 |
|
Co-ThO2-kguhr............ |
100:18:100 |
392 |
16.97 |
Middle pressure. |
Co-ThO2-kguhr............ |
100:18:100 |
----- |
17.56 |
|
Co-Cu-MgO-sugar-char |
100:35:15:- |
473 |
.33 |
See footnote 1. |
Co-Cu-MgO-pumice.... |
100:35:15:- |
473 |
.50 |
See footnote 2. |
Co-Mn-Al-kguhr.......... |
100:15:5:- |
419 |
.57 |
|
Co-Mn-Cu-kguhr......... |
100:15:10:- |
401 |
.81 |
|
Co-Cu-MnO2-ThO2-kguhr............................ |
100:5:12:4:125 |
365-410 |
1.11 |
|
Co-Cu-ThO2-Ce-kguhr |
100:11:22:2.6:- |
392 |
.25 |
Ignition of nitrates gave slightly higher yield. |
Co-Cu-Th-starch-kguhr |
100:12.5:3.76:150:125 |
410 |
.83 |
|
Co-Cu-Th-U-kguhr...... |
100:12.5:1.88:1.88: 125 |
410 |
.50 |
|
Co-Cu-Th-U-kguhr...... |
10:12.5:1.88:1.88: 125 |
410 |
1.00 |
|
Co-Cu-U-starch-kguhr. |
100:12.5:3.76:150:150 |
414 |
.87 |
|
Co-Mg-Cu-Cr-(?)........ |
100:25:12.5:12.5:- |
410 |
.39 |
CO:H2=1:1. |
Co-Mg-Cu-Mo-(?)...... |
100:25:12.5:12.5:- |
410 |
.35 |
CO:H2=1:1. |
Co-Mg-Cu-Th-kguhr.... |
100:25:12.5:5:75 |
455 |
.42 |
|
Co-Mg-Cu-Th-(?)........ |
100:25:12.5:5:- |
410 |
.54 |
CO:H2=1:1. |
Co-Mg-Cu-U-(?)......... |
100:25:12.5:5:75 |
410 |
.56 |
CO:H2=1:1. |
Co-Mg-Cu-W-(?)........ |
100:25:12.5:5:- |
410 |
.44 |
CO:H2=2:3. |
Co-Mn-Cu-Th-kaolin... |
100:25:12.5:12.5:- |
471 |
.46 |
|
Co-Cu-Th-U-starch-kguhr............................ |
100:12.5:1.88:1.88: 150:125 |
410 |
.97 |
|
Co-Mg-Cu-Th-Co-(?).. |
100:30:10:5:0.77 |
455 |
.47 |
|
Co-Ni-Mn-U3O8-ThO2-kguhr............................ |
100:43:21:7:4:125 |
392 |
1.04 |
|
Co-Ni, Fe, CaO, S, Mn)-ThO2-kguhr.......... |
100(1.72):8 |
----- |
.84 |
Naphthene production (?). |
1 Lb. per 1,000 cu. ft.
2 Reference gives yield ten times larger. A source of error has been assumed.