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1483. HONDA, K., AND MURAKAMI, T. Thermomagnetic Properties of the Carbides Found in Steels. Sci. Repts. Tôhoku Imp. Univ., vol. 6, 1917, pp. 23-29; Chem. Abs., vol. 11, 1917, p. 2887.
To obtain the carbides, rods of C and W steels were annealed at 880°-920° and cooled very slowly. The rods were then polished and turned down until they were 7 mm. thick and 10 cm. long. The rods were used as anodes in dilute HCl, and by electrolysis the carbides were obtained. The Fe cementite was obtained as a gray powder and the double carbide as a black powder. The former contained 6.08% C and 93.5% Fe; the latter 8.10% C, 31.71% Fe, and 53.70% W. The Fe cementite is ferromagnetic and in a field of 500 gauss its specific magnetization is 19.7. The critical temperature, above which the carbide is paramagnetic, is 215°. In its free state the cementite is decomposed almost completely into its components by heating long enough at 900°. The double carbide found in low W-steels also is ferromagnetic, and its specific magnetization in a field of 500 gauss is 15.5. Its critical temperature lies at 400°. It is decomposed into its components by heating it to 850°. The conclusion, however, may not apply to the double carbide as it exists in low-W steel because its boundary condition is quite different in the steel than when existing by itself in the free state.