1269. GRISWOLD, J., CHU, P. L., AND WINSAUER, W. O. Separation of Synthesis Mixtures. Phase Equilibria in Ethyl Alcohol-Ethyl Acetate-Water System. Ind. Eug. Chem., vol. 41, No. 10, 1949, pp. 2352-2358; Chem. Abs., vol. 44, 1950, p. 1788. Above compounds occur in the water product of Fischer-Tropsch type hydrocarbon synthesis processes and in the manufacture of ethyl acetate by esterification. Vapor-liquid equilibria are reported for the AcOEt-EtOH and AcOEt-H2O binaries as well as for the ternary system. In addition d254 and boiling point (760 mm. Hg) are given. The 2-phase liquid region is explored for the AcOEt-H2O binary and for the ternary with tie-lines and isothermal boundaries reported. No well-defined ternary azeotrope was found, but a low-boiling zone at 70.3° covering a sizable range in ternary composition was reported along the ester-rich side of the 2-phase liquid region. GRODDE, K. H. See abs. 1270. GROH, E. See abs. 3101, 3102. GROLL, E. See abs. 1457. GROLL, H. See abs. 1453. GROSS. See abs. 1504. |