1259. ---------------. [GRIFFITH, R. H.] Geometrical Factor in Catalysis. Advances in Catalysts. Academic Press, Inc., New York, 1948, vol. I, pp. 91-114. Reaction kinetics and mechanism of catalysis are studied from the viewpoint of 2-point adsorption on an active catalyst surface. The reactions of unsaturated organic molecules and of C2H2 are discussed. The synthesis of hydrocarbons from CO, and related reactions, are argued, and evidence is brought forward to support the chain-growth hypothesis. See abs. 1465. |