1256. GRIFFIN, C. W. Adsorption of Hydrogen by Supported Nickel Poisoned With Carbon Monoxide. Jour. Am. Chem. Soc., vol. 59, 1937, pp. 2431-2434; Chem. Abs., vol. 32, 1938, p. 1158. Adsorption was measured at 0° for H2 on a supported Ni catalyst poisoned with CO. A small quantity of poison causes an increase of H2 adsorption at all pressures up to 1 atm. A large amount of poison gives a slight low-pressure increase and a high-pressure decrease of adsorption. Larger amounts of poison decrease the rate of adsorption. |