1227. GOTOH, Y. [Reduction of Ferric Oxide by Hydrogen and Oxidation of Metallic Iron Reduced From Ferric Oxide.] Mem. Ryojun Coll. Eng., Inouye Commemoration, vol. 1934, pp. 393-413; Chem. Abs., vol. 29, 1935, p. 2124. Describes apparatus for following changes of weight continuously by measuring the current required by a solenoid to counteract with displacement of a magnet attached to a silica spring, which is connected to a Pt bucket containing the sample. The material used was pure Fe2O3 and Anshan hematite, containing Fe2O3 93.89, Fe3O4 2.61, SiO2 2.42 and Al2O3 1.08%. The reduction takes place in the stages Fe2O3→Fe3O4→Fe. The reduction to Fe3O4 is rapid at all gas velocities; further reduction increases with increasing gas velocity up to 120 cc. per min. At constant gas velocity, the rate of reduction of Fe3O4 increases with the temperature, being rather slow up to 450°. The curves showed no breaks corresponding to FeO, and its absence was proved by X-ray photographs of samples at varying stages of reduction. GOTTLIEB, S. See abs. 924, 925. |