1144. GARNER, W. E., AND KINGMAN, F. E. T. Adsorption of Hydrogen and Carbon Monoxide on Oxide Catalysts. Nature, vol. 126, 1930, p. 352; Chem. Abs., vol. 24, 1930, p. 5567. H2 or CO adsorbed at room temperature on ZnO-Cr2O3 catalysts was given off at 100°-120° but after 20-30 min. was readsorbed on the surface of the catalysts. On raising the temperature further, no gas was given off up to 350°, when H2O or CO2 was liberated. Physically adsorbed gas must leave the surface before it can chemically combine with metallic oxides. |