1118. FUNASAKA, W., AND FUKUSHIMA, R. Removal of Organic Sulfur Compounds From Gas Mixtures for Synthesis. X. Influence of Impurities on the Purification of Industrial Gases. Jour. Soc. Chem. Ind. (Japan), vol. 50, 1947, pp. 122-124; Chem. Abs., vol. 44, 1950, p. 9136. Studies were made on the influence of various gases on the removal of organic S compounds from industrial gases. C2H4 had a deleterious effect on Fe and Al catalysts but not on Ni and Cu at 250°. At 400° no effect was detectable. C6H6 had no effect, while C2H2 had a deleterious effect. Acidic gases, such as CO2 or HCN, transformed CS2 to H2S, especially at high temperature. A high CO2 content had a deleterious effect at high temperatures. HCN also had a deleterious effect. Air, N2, and water vapor gave good results. Superimposed effects of various impurities were complicated. |