1099. FROLICH, P. K., FENSKE, M. R., TAYLOR, P. S., AND SOUTHWICK, C. A. Catalysts for the Formation of Alcohols From Carbon Monoxide and Hydrogen. II. Synthesis of Methanol With Catalysts Composed of Copper and Zinc. Ind. Eng. Chem., vol. 20, 1928, pp. 1327-1330; British Chem. Abs., 1929, A, p. 153; Chem. Abs., vol. 23, 1929, p. 816. Data on the decomposition of MeOH by CuO-ZnO catalysts at atmospheric pressure have been correlated with experiments on MeOH synthesis at 204 atm., the same catalysts being used. The curves for “% of decomposed MeOH appearing as CO” vs. “composition of catalyst” are of the same shape as those representing “% of CO converted to MeOH” plotted against the same abscissas. Conclusion: The atmospheric pressure decomposition method of testing is eminently fitted for studies of the activity of catalysts for the MeOH synthesis from water gas at high pressure. |