1090. FRIEDEL, R. A., AND ANDERSON, R. B. Composition of Synthetic Liquid Fuels. I. Product Distribution and Analysis of C5-C8 Paraffin Isomers From Cobalt Catalyst. Jour. Am. Chem. Soc., vol. 72, 1950, pp. 1212-1215, 2307. Distribution of Fischer-Tropsch synthesis products has been given C1-C29 for precipitated Co catalysts, using H2 : CO = 2:1 at atmospheric pressure and 190°. Quantitative analysis of C5-C8 paraffin isomers by mass spectrometry showed only the presence of monomethyl isomers. The predominant components, the straight-chain isomers, decreased with increasing molecular weight. Approximate analyses of olefins showed that internal doublebond olefins were the major constituents. Preliminary results on Fe-catalyst products also are reported. |