1087. FRICKE, R., AND ACKERMANN, P. [Heat Content and Lattice Structure of Active Ferric Oxide.] Ztschr. Elektrochem., vol. 40, 1934, pp. 630-640; Chem. Abs., vol. 29, 1935, p. 33. The lower the temperature of dehydration of synthetic microcrystalline a-FeOOH, the greater is the energy content of the resulting a-Fe2O3; the energy differences as shown by heats of solution may reach 5 kcal. per mol. Fe2O3. Quantitative photometric measurements of x-ray powder photographs show imperfect lattice formation of the low-temperature Fe2O3, rather than differences in particle size or in lattice dimensions relative to the high-temperature Fe2O3. Tempering at 220° increases the lattice perfection of low-temperature Fe2O3 and restores its energy content to normal. |