1056. FORRESTIER, H., AND KIEHL, J. P. [Effect of Gaseous Adsorption on the Velocity of Reaction of Metallic Oxides.] Compt. Rend., vol. 229, 1949, pp. 47-49; Chem. Abs., vol. 44, 1950, p. 403. Yields of ferrite from powdered Fe2O3 and NiO heated in atmospheres of H2O, CO2, O2, air, N2, Ne, A, and He at 600°, 650°, and 700° plotted as isotherms against absolute temperature of liquefaction of the gases give smooth curves except for N2, which gives a low yield. Yields decrease with particle size. The explanation advanced is that the gases are most readily adsorbed in the order named, and adsorption swells the particles till they shatter. |