1030. FISCHER, F., BAHR, T., AND MEUSEL, A. [Catalytic Reduction of Carbon Dioxide to Methane and Higher Hydrocarbons at Ordinary Pressure. Preliminary Communication.] Brennstoff-Chem., vol. 16, 1935, pp. 466-469; Ges. Abhandl. Kenntnis Kohle, vol. 12, 1937, pp. 263-270; Chem. Abs., vol. 30, 1936, p. 3967. When Ru powder or Ru-Th asbestos is used as contact catalyst, CO2 may be appreciably reduced to CH4 from 100° upward. Addition of CaCO3 or Rb2CO3 results in the formation, from 170° upward, of higher gaseous and fluid hydrocarbons. Weaker alkalies do not have this effect on the catalyst. |