1027. FISCHER, F., AND WANGENHEIM, F. [Reactions Between Carbon Monoxide, Carbon Dioxide and Hydrogen in a “Cold-Warm” Tube at Atmospheric and High Pressure.] Brennstoff-chem., vol. 9, 1928, pp. 94-97; Ges. Abhandl. Kenntnis Kohle, vol. 9, 1930, pp. 570-579; British Chem. Abs., 1928, B, p. 355; Chem. Abs., vol. 22, 1928, p. 4323. Special steel bomb is used in which the contact metals serve as electric resistors. Metals used were: Fe, Ni, W, Mo, and also C, named in order of their catalytic activity. Various mixtures of CO and CO2 with H2 were used. C was produced and also CH4 with traces of higher homologs in some cases. Traces of HCHO were formed but no CH3OH. Temperatures of 550°-800° were used. |