1023. --------------. [Formation of Synthol on Carrying Out the Petroleum Synthesis Under Pressure and the Synthesis of Hydrocarbons of High Molecular Weight From Water Gas.] Brennstoff-Chem., vol. 8, 1927, pp. 165-167; Ges. Abhandl. Kenntnis Kohle, vol. 8, 1929, pp. 209-214; Chem. Abs., vol. 22, 1928, p. 497. Results are reported from which it seems clear that products obtained catalytically at pressures of 10-15 atm. are intermediate in character. They were neither exclusively hydrocarbons, as in the atmospheric pressure synthesis, nor mainly oxygenated compounds, as the high-pressure synthol synthesis. A disadvantage of working at 10-15 atm. is that paraffins of high molecular weight are retained by the catalyst, rendering it inactive in time. A paraffin, C70H144 was isolated. |